Thermometric property:
It is a physical property
that varies continuously with temperature.
Thermometric properties can be
used to measure the temperature.
For example imagine a closed constant volume(no change in dimension) tube on a heater, as the temperature increases the pressure also increases. later when you remove the tube temperature decreases steadily with decrease in pressure inside the tube. here as the temperature is varying with pressure, by measuring the pressure and by applying the value in ideal gas equation we can find value of temperature. As the temperature is measured with the help of pressure, pressure is considered as the Thermometric property.
similarly below are few thermometric properties for respective thermometers.
Type of thermometer
|
Principle
|
Thermometric property
|
Resistance
|
Wheat stone bridge
|
Resistance
|
Thermocouple
|
See back effect
|
E.M.F
|
Constant volume gas thermometer
|
Ideal gas equation (PV=MRT)
|
Pressure
|
Constant pressure gas thermometer
|
Ideal gas equation (PV=MRT)
|
Volume
|
for mercury thermometer length is considered to be thermometric property.
Method of temperature measurement
method used before 1954:
T=[100(P-Pi)] / (Ps-Pi)
here T= temperature
P=
pressure corresponding to temperature T
Pi= pressure corresponding to ice point (273K)
Ps= pressure corresponding to steam point (373K)
Pi= pressure corresponding to ice point (273K)
Ps= pressure corresponding to steam point (373K)
Using Ice point & Boiling
point of water the thermometer can be calibrated.
method after 1954:
T=273.16(P/Ptp)where T=temperature,P= Property(volume or pressure) corresponding to temperature T,Ptp= Property(volume or pressure) corresponding to triple point temperature.
Triple point of water:
It is the point where all the phases (gas,liquid,solid) coexist. for water its value is 273.16K or 0.01 degree centigrade.

No comments:
Post a Comment